What does the brackets around [H+] and [OH-] represent and what does it do?? (this is in context to acids and bases)

1 Answer
Apr 15, 2018

In this context, the brackets means concentration...

Explanation:

It is tempting to assume that HO and H3O+ are actual species in aqueous species. As far as anyone knows these species are CLUSTERS of water molecules LESS or PLUS a proton...

And so HO/H+ or HO/H3O+ are likely to be H5O+3 or H7O4 or ...or something...we use the HO/H3O+ as a label of convenience...the acidium species is a water cluster associated with an extra proton, and the hydroxide species is a water cluster LESS a proton. And if you play rugby think of H+ as the ball in a maul.

But certainly, when we do acid-base titrations, we can find the equivalence of acids and bases, straightforwardly and quantitatively, using very simple equipment, calibrated burettes, and standard indicatos.

And we use the brackets to designate a concentration term: [H3O+][HO]=1014 under standard conditions. And for simplicity, when we see [H3O+] or [NO3] or [Cl], we mean the concentration of acidium ion, or nitrate ion, or chloride in molL1...