What does this structure mean ? what are use of charges ? please explain

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1 Answer
Jun 29, 2018

Well, you have got #"COT dianion..."#, #C_8H_8^(2-)#

Explanation:

That is you got the dianion of the mollykewell cyclo-octatetraene as shown...

![coleplamer.com](useruploads.socratic.org)

This has EIGHT #pi"-electrons"# and is formally anti-aromatic..(i.e. it does not fulfil the Huckel criteria for aromaticity...) In order to avoid this unfavourable condition..the ring buckles to give a so-called tub shape...

![http://thestudentroom.co.uk](https://useruploads.socratic.org/Qaq2WDJsRlq85lVrecgj_COT_3.png)

However, the ring can be READILY reduced...by two equiv of alkali metal to give a formal dianion....with #"10# #pi# #"electrons"#...i.e. #C_8H_8^(2-)#...cyclo-octatetraenyl dianion... Such an electronic structure fulfils the Huckel criterion, and this beast is planar and aromatic, and has an extensive coordination chemistry...especially with larger metals...

This is the #"uranium(IV) derivative"#, so-called #"uranocene"#...the uranium analogue of ferrocene..., i.e. #[U(eta^8-C_8H_8)_2]#

![fr.wikipedia.org](useruploads.socratic.org)

The #C-C# bond lengths are all equivalent, and intermediate between #C-C#, #1.54xx10^-10*m#, and #C=C#, #1.34xx10^-10*m#....