What element has the smallest atomic radius?

1 Answer
Oct 29, 2016

Atomic size decreases across a Period, but INCREASES down a Group.

Explanation:

And thus the element with the smallest atomic radius should be "helium, Z=2".

This site reports that the atomic radius is 31xx10^-12m, where the atomic radius of the hydrogen atom is 53xx10^-12m.

That atomic size should decrease across a Period from left to right as we face the Table, can be attributed to the increase of nuclear charge (i.e. the increase in Z), versus the inability of incomplete electronic shells to shield the nuclear charge effectively. The helium atom is smaller than the hydrogen atom, because the nuclear charge is greater, and the 2 electrons occupy the same orbital as does the single electron in the hydrogen atom.

This is a fundamental principle of inorganic chemistry.