What is a numerical value of the ratio of products to reactants, only at a specified temperature is called?

1 Answer
Aug 30, 2017

Well, equilibrium constants are temperature-dependent.

K = ([C]^c[D]^d)/([A]^a[B]^b)K=[C]c[D]d[A]a[B]b

for the reaction

overbrace(aA + bB)^"reactants" rightleftharpoons overbrace(cC + dD)^"products",

where a, . . . , d are the stoichiometric coefficients of corresponding substances A, . . . , D.

And with temperature variations, we get a change in the value of K. Higher temperatures favor the forward reaction for endothermic reactions and the backward reaction for exothermic reactions.

It is known that K_w varies directly (as opposed to inversely) with temperature, as the autoionization of water is endothermic (involves breaking an "O"-"H" bond!).

And thus, "pH" and "pH" are also temperature-dependent. [See here.](https://socratic.org/questions/do-acids-have-ph-above-7)