What is a quantum harmonic oscillator?

1 Answer
Nov 5, 2016

The quantum harmonic oscillator is essentially a two-body problem consisting of two solid spheres connected by a spring.

A basic version of it is called the simple harmonic oscillator (SHO), in which the spring has no dampening factor (no anharmonicity constant):

![hyperphysics.phy-astr.gsu.edu)

Since there is no dampening factor, the energy levels are evenly spaced, separated by ℏomega, or hnu (the anharmonic oscillator would have quadratic convergence of the energy levels). Furthermore, the lowest energy level is 1/2ℏomega, and not 0.

The Hamiltonian operator for the SHO system in one dimension is:

color(blue)(hatH_"SHO") = hatK + hatV

= -ℏ^2/(2mu)d^2/(dx^2) + 1/2kx^2

= [-iℏd/(dx)]^2/(2mu) + 1/2kx^2

= color(blue)(hatp^2/(2mu) + 1/2kx^2)

where mu = (m_1m_2)/(m_1 + m_2) is the reduced mass, hatp is the momentum operator, k is the force constant, and x is the relative displacement from equilibrium. hatK and hatV were the kinetic and potential energy operators.

The normalized wave function for the upsilonth energy level in general is the product of a Hermite polynomial and a decaying exponential.

color(blue)(psi_(upsilon)(x) = N_(upsilon)H_(upsilon)(sqrtalphax)e^(-alphax^2"/"2))

where:

  • N_(upsilon) = [1/(2^(upsilon) upsilon!)(alpha/(pi))^"1/2"]^"1/2" is the normalization constant.
  • H_(upsilon)(sqrtalphax) = (-1)^(upsilon)e^(-alphax^2)d^(upsilon)/(d (sqrtalphax)^(upsilon))[e^(-alphax^2)] is the Hermite polynomial.
  • alpha = sqrt((kmu)/(ℏ^2)) is a variable defined for convenience of expressing the function.

Applying the variational method on some trial wave function, psi_0(x) = Ne^(-cx^2), where N = ((2c)/pi)^"1/4" upon normalization, would give you:

color(blue)(E_0 = 1/2ℏomega)

which is in general,

bb(E_(upsilon) = ℏomega(upsilon + 1/2)),

as shown in the first image.