What is meant by partial pressure of oxygen?

1 Answer
Feb 10, 2017

In a gaseous mixture, the "partial pressure" of a gas is the pressure that gas would exert if it ALONE occupied the container.

Explanation:

The total pressure is the sum of the individual partial pressures.

And so when we have a gaseous mixture of several gases, A, B, and C.........

P_"Total"=P_A+P_B+P_C...................

And to assess P, we may simply use the ideal gas equation:

P_"Total"= (n_ART)/V+(n_BRT)/V+(n_CRT)/V...................

P_"Total"=(RT)/V{n_A+n_B+n_C..............}

and clearly, P_A=P_A/P_"Total"=n_A/{n_A+n_B+n_C..............}

And thus the partial pressure of a component is proportional to the mole fraction of that component.

The air we breathe now is approx. 1*atm pressure (unless you live in Denver).

And thus P_"Total"=P_"dioxygen"+P_"dinitrogen"+P_"other gases"

And so P_"dioxygen"=0.20*atm. P_"dinitrogen"=0.78*atm

P_"dinitrogen"+P_"dioxygen"~=1*"atm"