What is the oxidation number of chlorine atom in HClHCl, Cl_2Cl2, and HClOHClO?

1 Answer
Jan 1, 2017

In HClHCl we have Cl(-I)Cl(I).............

Explanation:

In Cl_2Cl2, Cl(0)Cl(0), and in HClOHClO, Cl(+I)Cl(+I).

The oxidation number is the charge left on the central atom when all of the bonds are removed, with the charge devolved to the most electronegative atom.

For a homonuclear diatomic molecules, each atom has EQUAL electronegativity, and the charge is assumed to be shared; i.e. Cl_2 rarr 2xxCl*Cl22×Cl; HCl rarr H^+ + Cl^-HClH++Cl; HClO rarr H^(+I) + Cl^(+I)+O^(+II)HClOH+I+Cl+I+O+II.