What is the total pressure (mmHg) of a gaseous mixture of 3.7 g of hydrogen gas and 9.1 g of oxygen gas in a 3.24-L flask if the partial pressure of hydrogen is 318 mmHg?

1 Answer
Nov 25, 2016

Approx. 1.5*atm1.5atm.

Explanation:

Given constant temperature, and volume, which we certainly have here (even though we don't know their magnitudes), pressure is proportional to the number of moles of gas, or vice versa.

"Moles of dihydrogen"Moles of dihydrogen == (3.7*g)/(2.02*g*mol^-1)=1.83*mol3.7g2.02gmol1=1.83mol.

"Moles of dioxygen"Moles of dioxygen == (9.1*g)/(32.00*g*mol^-1)=4.97*mol9.1g32.00gmol1=4.97mol.

We are given that P_"dihydrogen"=318*mm*Hg=(318*mm*Hg)/(760*mm*Hg*atm^-1)=0.418*atmPdihydrogen=318mmHg=318mmHg760mmHgatm1=0.418atm

And given the proportionality between moles and pressure,

P_"dioxygen"=(4.97*mol)/(1.83*mol)xx0.418*atm=1.135*atmPdioxygen=4.97mol1.83mol×0.418atm=1.135atm.

And finally, P_"Total"=P_"dihydrogen"+P_"dioxygen"PTotal=Pdihydrogen+Pdioxygen

== (0.418+1.135)*atm(0.418+1.135)atm

Note that I converted the mm*HgmmHg to units of "atmospheres"atmospheres, because I really don't think mm*HgmmHg should be used for pressures much above 1*atm, i.e. 760*mm*Hg1atm,i.e.760mmHg. There seems to be quite a few questions on these boards where mercury columns greater than 760*mm*Hg760mmHg have been used to measure pressure. Obviously, the person who set the question has never had to clean up a mercury spill.