Why doesn't barium nitrate react with sulfuric acid?

1 Answer
Mar 6, 2016

It does react with sulfuric acid!

Explanation:

Barium nitrate, "Ba"("NO"_3)_2Ba(NO3)2, will react with sulfuric acid, "H"_2"SO"_4H2SO4, to produce barium sulfate, "BaSO"_4BaSO4, and aqueous nitric acid, "HNO"_3HNO3.

Barium sulfate is insoluble in water and will precipitate out of solution.

The balanced chemical equation for this double replacement reaction looks like this

"Ba"("NO"_3)_text(2(aq]) + "H"_2"SO"_text(4(aq]) -> "BaSO"_text(4(s]) darr + 2"HNO"_text(3(aq])Ba(NO3)2(aq]+H2SO4(aq]BaSO4(s]+2HNO3(aq]

The complete ionic equation for this reaction looks like this

"Ba"_text((aq])^(2+) + 2"NO"_text(3(aq])^(-) + 2"H"_text((aq])^(+) + "SO"_text(4(aq])^(2-) -> "BaSO"_text(4(s]) darr + 2"H"_text((aq])^(+) + 2"NO"_text(3(aq])^(-)Ba2+(aq]+2NO3(aq]+2H+(aq]+SO24(aq]BaSO4(s]+2H+(aq]+2NO3(aq]

To get the net ionic equation, eliminate spectator ions, i.e. the ions that are present on both sides of the equation

"Ba"_text((aq])^(2+) + color(red)(cancel(color(black)(2"NO"_text(3(aq])^(-)))) + color(red)(cancel(color(black)(2"H"_text((aq])^(+)))) + "SO"_text(4(aq])^(2-) -> "BaSO"_text(4(s]) darr + color(red)(cancel(color(black)(2"H"_text((aq])^(+)))) + color(red)(cancel(color(black)(2"NO"_text(3(aq])^(-))))

This will give you

"Ba"_text((aq])^(2+) + "SO"_text(4(aq])^(2-) -> "BaSO"_text(4(s]) darr

Barium sulftate is a white insoluble solid that precipitates out of solution.

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