Why is CO a lewis acid?

1 Answer
Jan 16, 2016

CO can act as a Lewis acid because it has a low-lying, vacant, antibonding π orbital that can accept electrons from an electron-pair donor.

Explanation:

The antibonding orbital looks like the image below.

upload.wikimedia.org

An example is nickel tetracarbonyl, Ni(CO)4, in which the vacant π orbital on the carbon monoxide has the right symmetry and the right energy to accept electron density from a filled d orbital of the metal in a process called back-bonding*.

i.ytimg.com

Because the carbon monoxide is accepting electron density, it is behaving as a Lewis acid.