Question #bb66f

2 Answers
Jun 15, 2016

Here's what I got.

Explanation:

A radioactive nuclide's nuclear half-life is defined as the time needed for half of an initial sample to undergo radioactive decay.

My own work

If you take "N"_0N0 to be the initial concentration of your radioactive nuclide "X"X, you can say that you will be left with

1/2 * "N"_0 = "N"_0/2 -> 12N0=N02 after the passing of one half-life

1/2 * "N"_0/2 = "N"_0/4 ->12N02=N04 after the passing of two half-lives

1/2 * "N"_0/4 = "N"_0/8 ->12N04=N08 after the passing of three half-lives
vdots

and so on.

This means that you can express the amount of the nuclide that remains undecayed after a period of time tt like this

color(blue)(|bar(ul(color(white)(a/a)"N"_t = "N"_0 * 1/2^ncolor(white)(a/a)|)))" " " "color(orange)("(*)")

Here

n - the number of half-lives that pass in the given period of time t

All you have to do now is pick a period of time t and use the known ratio that exists between "N"_t and "N"_0 to find n.

For example, for t=0 -> t="5 h" you have

"N"_t/"N"_0 = 1/2^n = 0.6484

This is equivalent to

2^n = 1/0.6484

ln(2^n) = ln(1/0.6484)

n * ln(2) = ln(1/0.6484) implies n = ln(1/0.6484)/ln(2) = 0.625

So, you know that 0.625 half-lives pass in 5 hours, which means that the half-life of the nuclide, t_"1/2", is

t_"1/2" = "5 h"/0.625 = color(green)(|bar(ul(color(white)(a/a)color(black)("8 h")color(white)(a/a)|)))

I recommend using different time periods to find n, the half-life must come out the same in every case. That is the case because radioactive decay is a first-order reaction, meaning that its half-life is constant throughout the decay process.

For example, for t=0 -> t = "18 h" you have

"N"_t/"N"_0 = 0.2102

This time you get

n = ln(1/0.2102)/ln(2) = 2.25

Once again, you have

t_"1/2" = "18 h"/2.25 = "8 h"

For the second part, use the half-life of the reaction to find the value of n

n = (64 color(red)(cancel(color(black)("h"))))/(8color(red)(cancel(color(black)("h")))) = 8

then use equation color(orange)("(*)") to find the mass of the nuclide that remains undecayed

"N"_t = "2.500 mg" * 1/2^8

"N"_t = "0.009766 mg"

This means that the amount of the nuclide that decayed is

"N"_"decayed" = "2.500 mg" - "0.009766 mg" = color(green)(|bar(ul(color(white)(a/a)color(black)("2.490 mg")color(white)(a/a)|)))

I'll leave the answer rounded to four sig figs.

Oct 20, 2016

The half life is 8 hours.

Explanation:

O.K., this is actually one that requires almost no math to solve!

As you know, or are learning, a half-life is the amount of time it takes for half of a radioactive element to decay. So, in the language of your question Nt/N0 = 0.5 at one half life.

Looking at your chart, we see that that happened somewhere between 5 and 10 hours.

Now we also know that after two half lives Nt/N0 will be 0.25.

Woa!!!! THAT's ON THE CHART!!!! Awesome!

Two half-lives = 16 hours.. Therefore one half-life = 8 hours.

Wait! Does that check with the previous observation that the half-life will be between 5 and 10 hours? Yup! O.K.! We are in business!

On to part B! 64 hours is 64/8 half-lives = 8 half-lives. After 8 half-lives there will be 1/2^8 of the original substance remaining. or 0.00390625 * original mass remaining. So we have lost (2.500 - (0.00390625*2.500)) grams, or 2.4902 grams of the original material.