Question #f9471

1 Answer
Jun 18, 2017

The mass of the original sample was 60.1 g.

Explanation:

Radioactive decay is a first order process.

Calculate the first-order rate constant

t_½ = ln2/k

k = ln2/t_½ = ln2/"2.62 h" = 0.2645 color(red)(cancel(color(black)("h"^"-1"))) × (1 color(red)(cancel(color(black)("h"))))/"60 min" = 4.409 × 10^"-3"color(white)(l) "min"^"-1"

Calculate the original mass

The integrated rate law for a first order reaction is

color(blue)(bar(ul(|color(white)(a/a)ln("A"_0/"A"_t) = ktcolor(white)(a/a)|)))" "

where

"A"_0 and "A"_t are the amounts at time t = 0 and at time t and

k is the rate constant

In your problem,

"A"_t = "47.1 g"

k = 4.409 × 10^"-3"color(white)(l) "min"^"-1"

t = "55.2 min"

ln("A"_0/"A"_t) = 4.409 × 10^"-3" color(red)(cancel(color(black)("min"^"-1"))) × 55.2 color(red)(cancel(color(black)("min"))) = 0.2434

"A"_0/"A"_t = e^0.2434 = 1.276

"A"_0 = 1.276"A"_t = "1.276 × 47.1 g = 60.1 g"

The original mass was 60.1 g.