Why is benzene aromatic?

1 Answer
Jun 29, 2017

Because it has 6 π electrons constrained, and delocalized around a ring.

Explanation:

Benzene satisfies the Huckel criterion, i.e. ; it has 4n+2=6 π electrons delocalized around a planar ring. This confers special stability, and special reactivity. While benzene is an aromatic carbocycle, heterocyclic aromatics exist, e.g. pyrrole, C4H4NH, furan, C4H4O, etc, in which the lone pairs on the heteroatom are delocalized.