By the Chain Rule, the first derivative is #y'=2e^{2x}-e^{x}# and the second derivative is #y''=4e^{2x}-e^{x}#. Inflection points occur at the values of #x# where the second derivative changes sign (from positive to negative or negative to positive).
Setting #y''=0# leads to #4e^{2x}-e^{x}=0#. The left-hand side of this equation can be factored as #e^{x}(4e^{x}-1)=0#. Since #e^{x}# is never zero, it follows that we just need to solve #4e^{x}-1=0# to get #x=ln(1/4)=-ln(4)\approx -1.386#.
You can check that #y''=4e^{2x}-e^{x}# changes sign at this point by graphing it. Therefore, there is an inflection point at #x=-ln(4)#. The second coordinate of this point can be found by plugging it into the original function to get #e^{2\cdot ln(1/4)}-e^{ln(1/4)}=1/16-1/4=-3/16#. The inflection point is therefore #(-ln(4),-3/16)#.